General Chemistry

Atoms and Molecules

Democritus’s ideas about atoms – The Greek philosopher Democritus (470–400 BC) suggested that all matter is composed of tiny, discrete, indivisible particles that he called atoms. – His ideas, based entirely on philosophical speculation rather than experimental evidence, were rejected for 2000 years. – By the late 1700s, scientists began …

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Heat and Temperature

Difference Between Heat and Temperature

Difference Between Heat and Temperature – Heat is one form of energy. – Many forms of energy can be interconverted and that in chemical processes, chemical energy is converted to heat energy or vice versa. – The amount of heat a process uses (endothermic) or gives off (exothermic) can tell …

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Solids, liquids, and gases.

Solids, liquids, and gases.

What’s the difference between Solids, liquids, and gases? – It is easy to tell the difference between solids, liquids and gases – A solid has a fixed shape and a fixed volume. It does not flow. Think of all the solid things around you: their shapes and volumes do not …

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Matter and Energy

Matter and Energy

Definition of Matter and Energy What is Matter? – Matter is anything that has mass and occupies space. – Mass is a measure of the quantity of matter  in a sample of any material. – The more massive an object is, the more force is required to put it in …

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Molecular Orbital Theory

Molecular Orbital Theory – The molecular orbital theory proposed by Hund and Mulliken in 1932 explains the formation of a covalent bond in a better way.  – According to molecular orbital theory all atomic orbitals of the atoms participating in molecule formation get disturbed when the concerned nuclei approach nearer. …

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Pauli Exclusion Principle

– The Pauli exclusion principle is of immense value in telling the maximum number of electrons accommodated in any shell. Quantum Numbers and the Energy of an Orbital – The nature of an electron, its position, and energy, is fully implied only by mentioning the values of four quantum numbers ascribed …

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Schrödinger Wave Equation

Schrödinger Wave Equation

Schrödinger Wave Equation – In order to provide sense and meaning to the probability approach, Schrödinger derived an equation known after his name as the Schrödinger Wave Equation.  – Calculation of the probability of finding the electron at various points in an atom was the main problem before Schrödinger.  – …

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Heisenberg’s uncertainty Principle

– Heisenberg’s uncertainty Principle: As it is impossible to know the position and the velocity of any one electron on account of its small size, the best we can do is to speak of the probability or relative chance of finding an electron with a probable velocity. Heisenberg’s Uncertainty Principle …

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