– In this subject we will talk about Structure and Classification of Alcohols. What are Alcohols? – Alcohols are organic compounds containing hydroxyl (-OH) groups. – They are some of the most common and useful compounds in nature, in industry, and around the house. – The word alcohol is one …
Read More »Reactions of Alkynes
Reactions of Alkynes – Many of the reactions of alkynes are similar to the corresponding reactions of alkenes because both involve pi bonds between two carbon atoms. – Like the pi bond of an alkene, the pi bonds of an alkyne are electron-rich, and they readily undergo addition reactions. (A) …
Read More »Oxidation of Alkynes
Before we discuss Oxidation of Alkynes we will talk about triple bond of Alkynes What are Alkynes? – Alkynes are hydrocarbons that contain carbon–carbon triple bonds. – Alkynes are also called acetylenes because they are derivatives of acetylene, the simplest alkyne – The chemistry of the carbon–carbon triple bond is …
Read More »Addition Reactions of Alkynes
Addition Reactions of Alkynes – Many of the reactions of alkynes are similar to the corresponding reactions of alkenes because both involve pi bonds between two carbon atoms. – Like the pi bond of an alkene, the pi bonds of an alkyne are electron-rich, and they readily undergo addition reactions. …
Read More »Synthesis of alkynes
Synthesis of alkynes – Two different approaches are commonly used for the synthesis of alkynes. – In the first, an appropriate electrophile undergoes nucleophilic attack by an acetylide ion. – The electrophile may be an unhindered primary alkyl halide (undergoes SN2), or it may be a carbonyl compound (undergoes addition …
Read More »Acidity of Alkynes : Formation of Acetylide Ions
Acidity of Alkynes: Formation of Acetylide Ions – Acidity of Alkynes is the inportant factor of activity of Alkynes. – Terminal alkynes are much more acidic than other hydrocarbons. – Removal of an acetylenic proton forms an acetylide ion, which plays a central role in alkyne chemistry. – The acidity …
Read More »The electronic structure of Alkynes
– we studied theThe electronic structureof Alkynes (a triple bond) in This subject: The Structure of Ethyne (Acetylene): sp Hybridization – Let’s review The electronic structureof Alkynes, using acetylene as the example. – The Lewis structure of acetylene shows three pairs of electrons in the region between the carbon nuclei: …
Read More »Importance of Alkynes : Acetylene
Commercial Importance of Alkynes : Acetylene and Methylacetylene Uses of Acetylene and Methylacetylene – Acetylene is by far the most important commercial alkyne. – and Acetylene is an important industrial feedstock, but its largest use is as the fuel for the oxyacetylene welding torch. – It is a colorless, foul-smelling …
Read More »Nomenclature of Alkynes
What are Alkynes? – Alkynes are hydrocarbons that contain carbon–carbon triple bonds. – Alkynes are also called acetylenes because they are derivatives of acetylene, the simplest alkyne – The chemistry of the carbon–carbon triple bond is similar to that of the double bond. – Alkynes undergo most of the same …
Read More »Reactions of Alkenes
– In this subject we will discuss all famous reactions of alkenes. – The reactions of alkenes include five basic methods as follow: (1) Electrophilic Additions (a) Addition of hydrogen halides – A Russian chemist, Vladimir Markovnikov, first showed the orientation of addition of HBr to alkenes in 1869. – …
Read More »Olefin Metathesis
Olefin Metathesis – The double bond is the strongest bond in an alkene, yet it is also the most reactive bond. – Imagine how useful it would be if we could break molecules at their double bonds and reassemble them as we please. That is the goal of olefin metathesis. …
Read More »Polymerization of Alkenes
Polymerization of Alkenes – A polymer is a large molecule composed of many smaller repeating units (the monomers) bonded together. – Alkenes serve as monomers for some of the most common polymers, such as polyethylene, polypropylene, polystyrene, poly(vinyl chloride), and many others. – Alkenes polymerize to give addition polymers resulting …
Read More »Oxidative Cleavage of Alkenes
Oxidative Cleavage of Alkenes Cleavage by Permanganate – In a potassium permanganate dihydroxylation, if the solution is warm or acidic or too concentrated, oxidative cleavage of the glycol may occur. – In effect, the double bond is cleaved to two carbonyl groups. – The products are initially ketones and aldehydes, …
Read More »Syn Dihydroxylation of Alkenes
Syn Dihydroxylation of Alkenes – Converting an alkene to a glycol requires adding a hydroxyl group to each end of the double bond. This addition is called Dihydroxylation of Alkenes or dihydroxylation (or hydroxylation) of the double bond. – We have seen that epoxidation of an alkene, followed by acidic …
Read More »Chemical Bonding – Orbital Concept – MCQ test
Online MCQ test on Chemical Bonding – Orbital Concept – In this topic we offer you, online MCQ test in the fundmental of Chemical Bonding – Orbital Concept. – It is a simple test to measure the strength of your knowledge in the basics of understanding the topics of Chemical …
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